Phosphaalkenyl germylenes and their gold, tungsten and molybdenum complexes.

نویسندگان

  • Dimitri Matioszek
  • Tibor-Gabor Kocsor
  • Annie Castel
  • Gabriela Nemes
  • Jean Escudié
  • Nathalie Saffon
چکیده

The new bis(phosphaalkenyl) germanium(II) compound (NHC)Ge(CCl=PMes*)(2) reacts with L(2)M(CO)(4) (M = Mo, W) to give bidentate complexes with an unexpected coordinating behaviour involving the Ge(II) centre and one phosphorus atom, and with AuI or Me(2)SAuCl to afford the monodentate complexes coordinated at the germanium(II) atom.

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عنوان ژورنال:
  • Chemical communications

دوره 48 30  شماره 

صفحات  -

تاریخ انتشار 2012